음.. 난 풀긴 했으니깐 어떻게 풀었는지 적어볼게;
틀렸으면 말해주세요~

일단 전체 엔트로피 변화는 혼합엔트로피랑 Cr2O3의 상변화에 따른 엔트로피를 합한게 될거야
1몰의 Cr2O3 를 Al2O3+Cr2O3 라울 용액에 넣은 것이니까
혼합 엔트로피는 Cr2O3의 배열 엔트로피에 해당 될거고,
근데 기존에 있던 애랑 들어간 애랑 같은 애니깐
혼합될때는 기존에 있던 것 까지 쳐서 혼합엔트로피를 구해- 누군지 구분안되니깐;
그럼 -RlnX(Cr2O3) 로 계산해야 하는데,
X(Cr2O3)는 다량의 용액에 1몰 넣은거라 -ㅅ-; 또, 소수 첫째자리까지밖에 없고;
변화가 거의 없을 거라고 생각하고 근사로 0.2로 계산했어-
그리고 상변화 할때 엔트로피를 더해주면 되/

엔탈피는 깁스 에너지식에서 구할 수 있어-

대충 내생각은 이래^^;

-_ㅠ 상변화 엔트로피를 조건 없다고 못구하고 있는데 ㅠ.ㅠ

조건에 엔트로피 변화가 Al 뭐시기랑 같다고 되있군 .ㅠㅠ

엔탈피를 다르게 구하면

이상용액에서는 믹싱엔탈피변화가 0이니까

용해될떄 총 엔탈피 변화는 상변화할떄 생기는 엔탈피만이라고 생각하고

문제에 있는 조건 이용해서 뒤에 테이블에서 Al~ 트랜스 엔탈피랑 트랜스 온도 찾아가지고

Al~ 트랜스엔탈피 / 트랜스 온도 = Cr~ 트랜스 엔탈피 / 트랜스 온도

로 Cr~의 트랜스 엔탈피 구해주고 요놈을 다시

온도로 나눠주면 Cr~의 트랜스 엔트로피도 나오던데용

요따가 위에 너구리씨가 말한 거 더해주면.

책에 답이랑 똑같이 나옵디다.

두 개 melting엔트로피가 같다는 이유가 저거였군요. 감사요~

지금 생각난건데 문제에서 dleta Cp 를 무시해야 문제가 풀리네요;

음음.. 어떤 거의 델타 Cp를 무시한다는 거야?

엔탈피의 변화는 상변화할때 생기는 엔탈핀데

2500도에서 상변화 엔탈피가 , 녹는점 에서의 엔탈피 변화와 같다고 가정해야 되는데

그럴려면 솔리드상태와 리퀴드 상태의 delta Cp 를 무시해야지;;

수지 답변 중에
'근데 기존에 있던 애랑 들어간 애랑 같은 애니깐 혼합될때는 기존에 있던 것 까지 쳐서 혼합엔트로피를 구해- 누군지 구분안되니깐; '
이게 이해가 안되는데? 1mol A를 A-B 용액에 넣는거랑 (1+X)mol의 A를 B 용액에 넣는거랑 혼합엔트로피가 같단 얘기야?

아. 이해했삼. 패스

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